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Classification and Sources of Fuels
Fossil Fuels
- Petroleum: A natural fuel.
- Natural Gas: A fossil fuel; considered the cleanest fossil fuel.
- Coal: A fossil fuel.
- Indian coal has a high ash content.
- Coal ash contains toxic elements (e.g., arsenic, lead, mercury).
- Furnace Oil: A processed product from oil refineries.
Processed & Synthetic Fuels
- From Coal:
- Coal Gas: A manufactured product (not natural). Major constituents: Hydrogen, Methane, Carbon Monoxide.
- Coke: A solid carbon-rich fuel produced from coal.
- Tar: A manufactured product from coal.
- Other:
- Water Gas: A manufactured mixture of Carbon Monoxide (CO) and Hydrogen (H₂); not a fossil fuel.
Gaseous Fuels
- Liquefied Petroleum Gas (LPG):
- Main components: Butane and Propane (main constituent is often Butane).
- Indane gas is a mixture of Butane and Propane.
- Supplied in cylinders in a liquid form.
- Biogas (including Gobar Gas):
- Primarily consists of Methane (CH₄) and Carbon Dioxide (CO₂).
- The ‘Gobar Gas’ system was invented by S.V. Desai.
- The production process is Fermentation.
- Compressed Natural Gas (CNG):
- Stands for Compressed Natural Gas.
- Major component: Methane (CH₄).
- Piped Natural Gas:
- Main component is Methane; can be supplied directly through pipelines.
- Liquefied Natural Gas (LNG):
- Natural gas liquefied under extremely cold temperatures and high pressure.
- Natural Gas Liquids (NGLs): Separated from LPG; include ethane, propane, butane, and natural gasoline.
- Gas Emitted from Rice Fields: Methane (CH₄).
Fuel Properties, Quality, and Environmental Impact
Fuel Quality Metrics
- Octane Number: Measures the quality of petrol (gasoline); indicates anti-knocking properties.
- Cetane Number: Measures the quality of diesel; indicates ignition delay time.
Fuel Efficiency and Value
- Highest Fuel Value: Hydrogen has the highest energy content per unit mass compared to charcoal, natural gas, and gasoline.
- Vehicle Fuel Efficiency: Features that improve efficiency include:
- Streamlined body (reduces air resistance).
- Multipoint fuel injection (improves combustion).
- Catalytic converter with exhaust (reduces emissions).
Environmental Impact
- Cleanest Fossil Fuel: Natural gas.
- Maximum Indoor Chemical Pollution: Caused by burning coal.
- Sulfur Emissions: Caused by the use of furnace oil.
- Power Plant Pollutants: Coal-fired power plants release sulfur dioxide (SO₂) and oxides of nitrogen (NOx).
- Copper Smelting Pollutants:
- Copper slag can cause leaching of heavy metals.
- Releases sulfur dioxide (SO₂).
Fuel Applications and Industrial Processes
Metallurgy (Blast Furnace)
- Fuel/Reducing Agent: Coke is used with two primary functions:
- Acts as a reducing agent.
- Functions as a fuel to supply heat.
- It does not act as an oxidizing agent.
Power Generation
- Furnace oil is used by some industries to generate power.
Engines
- Diesel Engine Fuel: The fuel used is a vapour of diesel and air.
Fuel Additives and Special Mixtures
Fuel Additives
- Anti-Knocking Agent: Tetraethyl Lead (TEL) was added to petrol to increase its octane rating.
- Safety Additive (LPG): Ethyl mercaptan is added to LPG to produce a stench for leak detection.
- Anti-Freeze Agent: Ethylene Glycol is used in automobile engines.
Fuel Mixtures
- Gasohol: A correct mixture of Gasoline (Petrol) and Ethyl Alcohol (Ethanol).
- Incorrect statement: “Gasohol is a mixture of benzene and alcohol” is false.
Clarifications and Corrections
True/False Clarifications
- “The main component of the liquefied petroleum gas is methane” is FALSE.
- “Methane can be used directly for burning in homes and factories where it can be supplied through pipelines” is TRUE.
General Science Facts
- Oxygen is absent in: Kerosene. (It may be present in soil, glass, and cement).
- Fossil Fuels: Coal, petroleum, and natural gas.
- Non-Conventional Energy Source: Geothermal energy.
Incorrect Facts (from provided options)
- The first LNG terminal in India was not built in Hassan. (The first was in Dahej, Gujarat).
- Hydrocarbon Vision 2025 was not primarily about the storage of petroleum products, Euro vehicles, or the Greenhouse effect. (It was a policy for the Indian oil and gas sector.)
Storage and Handling
- LPG Cylinders: Pressure gauges are not used on domestic LPG cylinders because pressure cannot represent the quantity of gas (it remains constant until the liquid evaporates); quantity is determined by weight.
- Hydrogen Storage: Hydrogen gas can be stored for vehicle fuel by being absorbed by Hydrides at low temperatures and released by heat.
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